PhotoElectric Effect


What's the photoelectric effect?

 


Here you can study the photo-electric effect.You can vary the voltage of the battery,choose a workfunction and also wavelength of incident light.

You can conduct several series of experiments:

Set the voltage to 0. Vary the wavelength. Observe the onset of the photo-current. What are the biggest wavelengths for materials with different work function, for which you still detect photo-current?
Set the voltage to 0. Go to a wavelength bigger than the onset point and vary the intensity of the light? Is there ever any photo-current? What if you raise the voltage?
Go to a wavelength smaller than the onset value and vary the voltage. Observe the resulting photo-current.


It's been determined experimentally that when light shines on a metal surface, the surface emits electrons. For example, you can start a current in a circuit just by shining a light on a metal plate. Why do you think this happens?

Well...we were saying earlier that light is made up of electromagnetic waves, and that the waves carry energy. So if a wave of light hit an electron in one of the atoms in the metal, it might transfer enough energy to knock the electron out of its atom.

Okay. Now, if light is indeed composed of waves, as you suggest... What do you mean, "if light is composed of waves"? Is there another option?

Historically, light has sometimes been viewed as a particle rather than a wave; Newton, for example, thought of light this way. The particle view was pretty much discredited with Young's double slit experiment, which made things look as though light had to be a wave. But in the early 20th century, some physicists--Einstein, for one--began to examine the particle view of light again. Einstein noted that careful experiments involving the photoelectric effect could show whether light consists of particles or waves.

How? It seems to me that the photoelectric effect would still occur no matter which view is correct. Either way, the light would carry energy, so it would be able to knock electrons around.

Yes, you're right--but the details of the photoelectric effect come out differently depending on whether light consists of particles or waves. If it's waves, the energy contained in one of those waves should depend only on its amplitude--that is, on the intensity of the light. Other factors, like the frequency, should make no difference. So, for example, red light and ultraviolet light of the same intensity should knock out the same number of electrons, and the maximum kinetic energy of both sets of electrons should also be the same. Decrease the intensity, and you should get fewer electrons, flying out more slowly; if the light is too faint, you shouldn't get any electrons at all, no matter what frequency you're using.

That sounds reasonable enough to me. How would the effect change if you assume that light is made of particles?

I should give you some background information on this, first. It all began with some work on radiation by Max Planck... In 1900, Max Planck was working on the problem of how the radiation an object emits is related to its temperature. He came up with a formula that agreed very closely with experimental data, but the formula only made sense if he assumed that the energy of a vibrating molecule was quantized--that is, it could only take on certain values.The energy would have to be proportional to the frequency of vibration, and it seemed to come in little "chunks" of the frequency multiplied by a certain constant. This constant came to be known as Planck's constant, or h, and it has the value =6.626*10 to the power of-34

That's a pretty small constant.

Yes, but it was an extremely radical idea to suggest that energy could only come in discrete lumps, even if the lumps were very small. Planck actually didn't realize how revolutionary his work was at the time; he thought he was just fudging the math to come up with the "right answer," and was convinced that someone else would come up with a better explanation for his formula.

I guess Einstein must have taken him seriously, though.

Quite seriously. Based on Planck's work, Einstein proposed that light also delivers its energy in chunks; light would then consist of little particles, or quanta, called photons, each with an energy of Planck's constant times its frequency.

In that case, the frequency of the light would make a difference in the photoelectric effect.

Exactly. Higher-frequency photons have more energy, so they should make the electrons come flying out faster; thus, switching to light with the same intensity but a higher frequency should increase the maximum kinetic energy of the emitted electrons. If you leave the frequency the same but crank up the intensity, more electrons should come out (because there are more photons to hit them), but they won't come out any faster, because each individual photon still has the same energy.

And if the frequency is low enough, then none of the photons will have enough energy to knock an electron out of an atom. So if you use really low-frequency light, you shouldn't get any electrons, no matter how high the intensity is. Whereas if you use a high frequency, you should still knock out some electrons even if the intensity is very low.

Quite right. Therefore, with a few simple measurements, the photoelectric effect would seem to be able to tell us whether light is in fact made up of particles or waves.

So did someone do the experiment? Which way did it turn out?

In 1913-1914, R.A. Millikan did a series of extremely careful experiments involving the photoelectric effect. He found that all of his results agreed exactly with Einstein's predictions about photons, not with the wave theory. Einstein actually won the Nobel Prize for his work on the photoelectric effect, not for his more famous theory of relativity.